Kinetics and mechanism of pyrophosphate metal complexes electroreduction
β Scribed by V.I. Kravtsov; V.V. Kondratiev
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 883 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0013-4686
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π SIMILAR VOLUMES
Recently a number of macrocyclic compounds have been discovered which are capable of forming complexes with alkali metal ions (for reviews see refs. 1-3). They belong to naturally occurring species as depsipeptides ~ or macrotetrolides z ,4 as well as to synthetic compounds like cyclic polyethers 3
The electroreduction behaviour of 1,2-, 1,4-, 1.3-dicyano-and 1,3,5-tricyanobenzenes in acetonitrile was investigated. The mechanism for the electroreduction of these compounds was proposed using the results of cyclic voltammetry, rotating disc voltammetry, dc and differential pulse polarography and