𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and mechanism of oxidation of primary alcohols by chloramine-T catalyzed by OsO4

✍ Scribed by K.V. Uma; S.M. Mayanna

Book ID
113176306
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
338 KB
Volume
61
Category
Article
ISSN
0021-9517

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Kinetics of oxidation of pantothenic aci
Kinetics of oxidation of pantothenic acid by chloramine-T in perchloric acid and in alkaline medium catalyzed by OsO4: A mechanistic approach
✍ Puttaswamy; R. V. Jagadeesh πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 129 KB

## Abstract Kinetics of oxidation of pantothenic acid (PA) by sodium __N__‐chloro‐__p__‐toluenesulfonamide or chloramine‐T (CAT) in the presence of HClO~4~ and NaOH (catalyzed by OsO~4~) has been investigated at 313 K. The stoichiometry and oxidation products are same in both media; however, their

Kinetics and mechanism of oxidation of d
Kinetics and mechanism of oxidation of dimethyl sulfoxide by chloramine-T in aqueous solution
✍ D. S. Mahadevappa; M. B. Jadhav; H. M. K. Naidu πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 569 KB

## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t