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Kinetics and mechanism of oxidation of (ethylenediaminediacetato)chromium(III) by N-bromosuccinimide

✍ Scribed by Ahmed A. Abdel-Khalek; Eman S. H. Khaled


Book ID
110243074
Publisher
Springer
Year
1999
Tongue
English
Weight
108 KB
Volume
24
Category
Article
ISSN
0340-4285

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In aqueous solutions, [Cr(en)3] 3+ aquates to [Cr(en)z-(H20)2] 3 Β§ A kinetic study of the oxidation of [Cr(en)3] 3+ by N-bromosuccinimide (NBS)in aqueous solutions and water-alcohol solvent mixtures was performed. The reaction is first order with respect to both total [Cr m] and [NBS]. The rate is i

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Oxidative kinetics of diethyl ketone in perchloric acid media in the presence of mercuric acetate have been studied by using N-bromosuccinimide (NBS) as oxidant in the temperature range of 25"-50"C. It has been found that the order with respect to NBS is zero while with respect to diethyl ketone and