𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and mechanism of oxidation of dimethyl sulphoxide by sodium bromate-sodium bisulphite reagent in aqueous medium

✍ Scribed by J. Viroopakshappa; V. Jagannadham

Book ID
110638255
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
2002
Tongue
English
Weight
47 KB
Volume
114
Category
Article
ISSN
0253-4134

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Kinetics and mechanism of oxidation of b
Kinetics and mechanism of oxidation of benzohydrazide by bromate catalyzed by vanadium(IV) in aqueous acidic medium
✍ S. A. Shewale; A. N. Phadkule; G. S. Gokavi πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 203 KB πŸ‘ 2 views

## Abstract The reaction between benzohydrazide and potassium bromate catalyzed by vanadium(IV) was studied under pseudo‐first‐order condition keeping large excess of hydrazide concentration over that of the oxidant. The initiation of the reaction occurs through oxidation of the catalyst vanadium(I

Kinetics and mechanism of oxidation of d
Kinetics and mechanism of oxidation of dimethyl sulfoxide by chloramine-T in aqueous solution
✍ D. S. Mahadevappa; M. B. Jadhav; H. M. K. Naidu πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 569 KB

## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t