The cerium(IV) oxidation of isobutanol, isoamyl alcohol isopropyl alcohol, and secondary butanol catalysed by chromium(III) was studied in sulphuric and perchloric acid mixture at 30 Β°C. The reaction was found to proceed with the formation of a chromium(IV) intermediate followed by its complexation
Kinetics and mechanism of oxidation of aromatic secondary alcohols by Tl(III) acetate
β Scribed by V S Srinivasan; N Venkatasubramanian
- Book ID
- 113005231
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 1978
- Tongue
- English
- Weight
- 539 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0253-4134
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π SIMILAR VOLUMES
The kinetics of oxidation of c~,/?-unsaturated alcohols (UA's), such as prop-2-ene-l-ol, but-2-ene-l-ol and 3phenyl-prop-2-ene-l-ol, by manganese(III) acetate in aqueous H2SO 4 at constant ionic strength and different acidities has been studied. The reaction was found to proceed through an outer sph
## Abstract The oxidative cleavage of some aliphatic ketoximes by thallium(III) acetate was studied in the temperature range of 20β40Β°C. The reactions were followed by determination of the rates of disappearance of thallium(III) acetate for variations in [substrate], [Tl(III)], [H^+^], ionic streng