The kinetics and mechanism of electron transfer between stable verdazyl radicals via bridge Mn(II), Co(II), Ni(II), Cu(I), and Zn ions have been studied in the range 280-330 K using the stopped-flow technique. It was found that the kinetic features of the reactions could be described in terms of the
Kinetics and mechanism of metal ion catalysis: Part I. Kinetics of electron transfer from cycloheptanone in aqueous alkali
โ Scribed by Satya P. S. Mehta
- Book ID
- 110246717
- Publisher
- Springer
- Year
- 2000
- Tongue
- English
- Weight
- 111 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0340-4285
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A kinetic reinvestigation of the title redox system in aqueous alkaline media at 35ยฐC and a n ionic strength of 0.5 mol dm-3 shows that the reaction follows a pseudosecondorder Fe(CN)i ~ disappearance. While varying LphenolIo and [OH 1 exhibit a linear influence on the pseudo-second-order rate const