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Kinetics and mechanism of mercury(II)-catalysed replacement of cyanide in hexacyanoferrate(II) by p-nitrosodiphenylamine

✍ Scribed by Madhu Fhull; P.C. Nigam


Book ID
118993550
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
526 KB
Volume
28
Category
Article
ISSN
0039-9140

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## Abstract The kinetics of Hg(II)‐catalyzed reaction between hexacyanoferrate(II) and nitroso‐R‐salt has been followed spectrophotometrically by monitoring the increase in absorbance at 720 nm, the Ξ»~max~ of green complex, [Fe(CN)~5~ N‐R‐salt]^3βˆ’^ as a function of pH, ionic strength, temperature,