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Kinetics and mechanism of exchange of cyanide in hexacyanoferrate(II) byN-methylpyrazinium ion in the presence of mercury(II) as a catalyst

✍ Scribed by Surendra Prasad


Book ID
110420862
Publisher
Springer
Year
2003
Tongue
English
Weight
225 KB
Volume
28
Category
Article
ISSN
0340-4285

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## Abstract The kinetics of Hg(II)‐catalyzed reaction between hexacyanoferrate(II) and nitroso‐R‐salt has been followed spectrophotometrically by monitoring the increase in absorbance at 720 nm, the Ξ»~max~ of green complex, [Fe(CN)~5~ N‐R‐salt]^3βˆ’^ as a function of pH, ionic strength, temperature,

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## Abstract The kinetics and mechanism of Hg^2+^‐catalyzed substitution of cyanide ion in an octahedral hexacyanoruthenate(II) complex by nitroso‐R‐salt have been studied spectrophotometrically at 525 nm (__Ξ»__~max~ of the purple‐red–colored complex). The reaction conditions were: temperature = 45.