Kinetics and mechanism of ligand substitution in iron tricarbonyl 1,4-diazabutadiene complexes
β Scribed by Shi, Qi Zhen; Richmond, Thomas G.; Trogler, William C.; Basolo, Fred
- Book ID
- 127194900
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 598 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
The reaction of neutral 1-substituted-tricarbonyl(q4-4-methoxycyclohexa-l,3-diene)iron complexes 3 with thallium(III) trifluoroacetate in alcoholic solution leads to the corresponding new 4-substituted-tricarbonyl(q 4cyclohexa-2,4-dien-l-one)iron complexes 4. A mechanism for this reaction is propose
Reaction of p-anisidine 13 or p-bromo orthoanisidine 14 with the new bi-deuterated dienyl complex 12 bearing a leaving group on its side chain affords the mono-deuterated 18a, 19a and the non-deuterated lgb and 19b spiro[1,2,3,4-tetrahydroquinoline-4,1'-cyclohexane] derivatives. The formation of the