Kinetics and mechanism of ligand substitution in tetrahedral zinc complexes
β Scribed by M. Dreher; H. Elias
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 101 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0020-1693
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The kinetics and mechanism of the removal of M2+ from bis-(heptane-2,4,6-trionato)M(II) [M = Ni, Co] by ethylenediminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), 1,2-cyclohexanediamine-N, N, N', N'tetraacetic acid (CyDTA), and ethylenebis(oxyethylenenitri1o)tetraacetic acid (EGTA) have bee
## Abstract The kinetics of the reaction have been studied in toluene solution. The reaction occurs by a dissociative mechanism and the observation of an appreciable mass law retardation effect shows that Fe(CO)~4~ is produced as an intermediate. Analysis of the effect of the substituent X on t