The following lines of evidence establish that oxime formation from pyruvic acid occurs with ratedetermining carbinolamine dehydration under acidic and neutral conditions. First, saturation effects observed at pH 7 are strongly suggestive of carbinolamine accumulation, requiring that dehydration of
β¦ LIBER β¦
Kinetics and mechanism of isobutene formation from T-butanol in hot liquid water
β Scribed by Xiaodong Xu; Michael J. Antal Jr.
- Publisher
- American Institute of Chemical Engineers
- Year
- 1994
- Tongue
- English
- Weight
- 989 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0001-1541
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## Abstract The evidence establishes that oxime formation from benzoylformic acid in the pH range from 0.25 to 5.5 occurs with acidβcatalyzed dehydration of carbinolamines derived from the acid and its anion. The pHβrate profile shows in order of decreasing pH in two regions: (1) In the pH range fr
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