Kinetics and mechanism of cobalt-catalyzed oxidation of p-xylene in the presence of water
β Scribed by Hronec, Milan; Cvengrosova, Zuzana; Ilavsky, Jan
- Book ID
- 125833524
- Publisher
- American Chemical Society
- Year
- 1985
- Weight
- 894 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0196-4305
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π SIMILAR VOLUMES
The aerobic liquid-phase oxidation of p-xylene (PX) over metalloporphyrin and Co(OAc) 2 was studied, and the co-catalysis between metalloporphyrin and Co(OAc) 2 for the oxidation of PX was discovered for the first time. The results showed that both the PX conversion and terephthalic acid yield could
The homogeneous metal/bromide-catalyzed aerobic oxidation of p-xylene with different catalyst concentrations was carried out, and the formation kinetics of CO x including CO 2 and CO was measured. The simplified elementary steps for the formation of CO x were summarized, on the basis of which the ki