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Kinetics and Mechanism of Captopril Oxidation in Aqueous Solution Under Controlled Oxygen Partial Pressure

✍ Scribed by Tak-Yee Lee; Robert E. Notari


Book ID
114421369
Publisher
Springer US
Year
1987
Tongue
English
Weight
860 KB
Volume
04
Category
Article
ISSN
0724-8741

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πŸ“œ SIMILAR VOLUMES


Kinetics and mechanism of oxidation of d
✍ D. S. Mahadevappa; M. B. Jadhav; H. M. K. Naidu πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 569 KB

## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t