Kinetics and mechanism of base hydrolysis of chromium(III) complexes with oxalates and quinolinic acid
β Scribed by Ewa Kita; Hasan Marai
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 400 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0340-4285
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π SIMILAR VOLUMES
Kinetics of multistep reaction of Cr(III) ions discharge to metal was studied on a stationary electrode and on a rotating disk electrode from the solutions containing formic acid or oxalic acid. The electroreduction of Cr(III) complex ions in aqueous solutions is shown to proceed via the formation o
The kinetics of the acid-catalysed hydrolysis of the [(imidazole)4Co(CO3) ] + ion was found to follow the rate law -dln[complex]/dt = k~K[H+]/(1 + K[H+]) in the 25-45 ~ range, [H +] 0.05-1.0 M range and I = 1.0 M. The reaction sequence consists of a rapid protonation equilibrium followed by the one-