Kinetics and mechanism of acrylonitrile polymerization by p-toluene sulfinic acid. I. Experimental
β Scribed by Amdur, Shimon ;Shavit, Nehemia
- Book ID
- 105340111
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2007
- Weight
- 625 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0449-2994
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## Abstract Radical polymerization of methacrylic acid (MAA) and acrylonitrile (AN) in the presence of pβnitrobenzyl triphenyl phosphonium ylide (pβNBTPy) in dimethyl sulphoxide at 65 Β± 0.1Β°C under inert atmosphere was investigated by dilatometry. The ylide failed to initiate the polymerization, bu
The kinetics of polymerization of acrylonitrile and methyl methacrylate initiated by the redox system 2,2'-thiodiethanol/trichloroaquobipyridylmanganese(III) have been investigated in the temperature range 20-35OC in dilute sulfuric acid. The oxidation of the substrate in the absence of monomer has