✦ LIBER ✦

Bulk polymerization of lactides initiated by aluminum isopropoxide. I. Mechanism and kinetics

✍ Scribed by Degée, Philippe; Dubois, Philippe; Jérǒme, Robert

Book ID: 121267818
Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 671 KB
Volume: 123
Category: Article
ISSN: 1022-1360
DOI: 10.1002/masy.19971230108

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Bulk polymerization of lactides initiate

Bulk polymerization of lactides initiated by aluminium isopropoxide, 3. Thermal stability and viscoelastic properties

✍ Philippe Degée; Philippe Dubois; Robert Jérôme 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 501 KB

## Abstract The thermal stability of poly(L‐lactide) and L/D‐lactide stereocopolymers polymerized in bulk with aluminium isopropoxide as initiator was investigated by thermogravimetric analysis, and time and temperature dependence of molecular weight and polydispersity. Compared to poly(L‐lactide)

Polymerization of l , l -Lactide Initiat

Polymerization of l , l -Lactide Initiated by Aluminum Isopropoxide Trimer or Tetramer

✍ Kowalski, Adam; Duda, Andrzej; Penczek, Stanislaw 📂 Article 📅 1998 🏛 American Chemical Society 🌐 English ⚖ 182 KB

Bulk polymerization of lactides initiate

Bulk polymerization of lactides initiated by aluminium isopropoxide, 2. Beneficial effect of lewis bases and transfer agents

✍ Philippe Degée; Philippe Dubois; Robert Jérôme 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 519 KB

## Abstract A high increase in the bulk polymerization rate of L,L‐lactide and racemic D,L‐lactide is observed when aluminium isopropoxide is added with an equimolar amount of a Lewis base, such as triphenylphosphine (P(ϕ)~3~) and better 4‐picoline (C~6~H~7~N). Polylactide of high molecular weight

Controlled Ring-Opening Polymerization o

Controlled Ring-Opening Polymerization of Lactones and Lactides Initiated by Lanthanum Isopropoxide, 1. General Aspects and Kinetics

✍ Maud Save; Michèle Schappacher; Alain Soum 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 494 KB 👁 2 views

Macromolecular engineering of polylacton

Macromolecular engineering of polylactones and polylactides. 4. Mechanism and kinetics of lactide homopolymerization by aluminum isopropoxide

✍ Dubois, P.; Jacobs, C.; Jerome, R.; Teyssie, P. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 591 KB

Kinetics of polymerization initiated by

Kinetics of polymerization initiated by peroxides containing heterocyclic groups. I. Kinetics of bulk polymerization of styrene and vinyl acetate initiated by difuroyl peroxide

✍ Molnar, S. 📂 Article 📅 1972 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 390 KB

## Abstract The rate and degree of bulk polymerization of styrene and vinyl acetate initiated by difuroyl peroxide and, for comparison, by dilauroyl and dibenzoyl peroxides were measured at several temperatures as a function of the initiator concentration. Also the rates of initiation were determin