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Kinetics and mechanism of acid-catalysed dissociation of tris(biguanide)rhodium(III) ion

✍ Scribed by D. Banerjea; B. Chattopadhyay

Book ID
115973299
Publisher
Elsevier Science
Year
1974
Weight
163 KB
Volume
36
Category
Article
ISSN
0022-1902

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The kinetics of the acid-catalysed hydrolysis of the [(imidazole)4Co(CO3) ] + ion was found to follow the rate law -dln[complex]/dt = k~K[H+]/(1 + K[H+]) in the 25-45 ~ range, [H +] 0.05-1.0 M range and I = 1.0 M. The reaction sequence consists of a rapid protonation equilibrium followed by the one-