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Kinetics and mechanism for the substitution reactions of monoaquamonochloro-(piperazine) palladium (II) complex with L-methionine and thiourea in aqueous solution

✍ Scribed by SHOUKRY, AZZA A

Book ID
120461149
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
2013
Tongue
English
Weight
471 KB
Volume
125
Category
Article
ISSN
0253-4134

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Kinetics and mechanisms of substitution
Kinetics and mechanisms of substitution reactions with sulphur-containing nucleophiles in aqueous acid solutions. II. Rates of reactions of some tetrahalopalladate(II) anions with some N-alkyl substituted thioureas
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## The rates and activation energy parameters of halide ligand substitution in PdXf (X = Cl-, Br-), with N-alkyl substituted thioureas in aqueous halo acid solutions have been determined for the first kinetically distinguishable step. Ligand and product composition is substantiated by analytical dat

Kinetics and mechanisms of substitution
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## Abstract The activation energy parameters for the reaction of PdX (X=Cl^βˆ’^, Br^βˆ’^) in aqueous halide acid solution with thiourea (tu) and selenourea (seu) have been determined. High rates of reaction parallel low enthalpies and appreciable negative entropy of activation. The rate law in each cas