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Kinetics and mechanism for pyruvic acid semicarbazone formation

โœ Scribed by Pino, Teresita; Cordes, E. H.

Book ID
126939732
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
394 KB
Volume
36
Category
Article
ISSN
0022-3263

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Kinetics and mechanism of oxime formatio
Kinetics and mechanism of oxime formation from pyruvic acid
โœ A. Malpica; M. Calzadilla; T. Cordova ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 61 KB ๐Ÿ‘ 2 views

The following lines of evidence establish that oxime formation from pyruvic acid occurs with ratedetermining carbinolamine dehydration under acidic and neutral conditions. First, saturation effects observed at pH 7 are strongly suggestive of carbinolamine accumulation, requiring that dehydration of