Kinetics and mechanism for methiocarb degradation by chlorine dioxide in aqueous solution
โ Scribed by Fang Tian; Zhimin Qiang; Chao Liu; Tao Zhang; Bingzhi Dong
- Book ID
- 118429108
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 485 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0045-6535
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๐ SIMILAR VOLUMES
## Abstract The mechanism by which an excess of iron(II) ion reacts with aqueous chlorine dioxide to produce iron(III) ion and chloride ion has been determined. The reaction proceeds via the formation of chlorite ion, which in turn reacts with additional iron(II) to produce the observed products. T
The problem of diethanolamine (DEA) degradation in gas-treating processes was quantified through a detailed kinetic study. This reaction was found to be catalyzed by COz, and degradation occurs in a successive manner to 3-(2-hydroxyethyl)oxazolidone-2, to N,N,N'-tris(2-hydroxyethyl)ethylenediamine a
as well as nonpolar systems. An effort is being made to obtain W without solubility data, with the possibility of finding a physicochemical basis for W and/or a group contribution method for estimating this solventsolute interaction term. It is interesting to observe in Table 111 and in Figs. 1 and