Kinetics and DFT studies on the reaction of copper(II) complexes and H2O2
β Scribed by Takao Osako; Shigenori Nagatomo; Teizo Kitagawa; Christopher J. Cramer; Shinobu Itoh
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 550 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1432-1327
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π SIMILAR VOLUMES
the radical oxy-Cope rearrangement. [17] For this purpose, the sulfoxide 10 was prepared from norbornenone 8 via the allylic alcohol 9 (the direct synthesis with the procedure of Evans et al. does not work in this particular case). By treating the sulfoxide 10 with Bu 3 SnH and azobisisobutyronitril
Through our flow injection analysis experiments, we discovered that an unsaturated complex of \(\mathrm{Cu}\) (II) and organic ligand had a strong catalytic effect on 1.10 -phenanthroline- \(\mathrm{H}_{2} \mathrm{O}_{2}-\mathrm{CTMAB}\) chemiluminescence reaction. Based on this mechanism, the new f