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Kinetic Study of the Two-Electron Oxidation of Cobalt Tetraneopentoxyphthalocyanine by Thionyl Chloride

✍ Scribed by Bernstein, P. A.; Lever, A. B. P.


Book ID
111862736
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
589 KB
Volume
34
Category
Article
ISSN
0020-1669

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Kinetic studies on the deaquation-anatio
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The deaquation-anation of solid aquapentamminecobalt(III) chloride was studied isothermally and nonisothermally. Kinetic data were obtained from t.g.a, and were analysed using 17 rate laws known for solid state reactions. This reaction, long interpreted as SN2, was found to obey an A1.5 rate law fro