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Kinetic studies on the deaquation-anation of aquapentammine-cobalt(III) chloride

✍ Scribed by Debbie Beck Hamilton; J. E. House

Book ID: 104636303
Publisher: Springer
Year: 1994
Tongue: English
Weight: 389 KB
Volume: 19
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf00136367

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✦ Synopsis

The deaquation-anation of solid aquapentamminecobalt(III) chloride was studied isothermally and nonisothermally. Kinetic data were obtained from t.g.a, and were analysed using 17 rate laws known for solid state reactions. This reaction, long interpreted as SN2, was found to obey an A1.5 rate law from both types of experiments. From the isothermal experiments, an Ea of 97.0 kJ mol-a was found.

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