## Abstract The reaction of copper with benzyl chlorides in dipolar aprotic solvents has been investigated. The kinetic and thermodynamic parameters of the reaction of copper with benzyl chloride in dimethyl sulfoxide, dimethylacetamide, and hexamethylphosphoramide have been obtained. Hammett plots
Kinetic study of the substitution reaction of benzyl chloride with triphenylphosphine to synthesize benzyltriphenylphosphonium chloride. Solvent effects
β Scribed by Wang, Maw Ling; Liu, Anhong; Jwo, Jing Jer
- Book ID
- 125508167
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 572 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0888-5885
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## Abstract We detected and studied CIDNP effects in the reaction of substituted benzyl chlorides with __n__βbutyllithium in hexane (Scheme 1) in various magnetic fields (from 0Β·5 Oe to about 25,000 Oe). The polarisation of ^19^F nuclei in the reaction of __p__βFβbenzyl chloride in strong fields ha