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Electrophilic aromatic substitution. 7. A kinetic study of the aluminum chloride catalyzed desulfonylative benzylation of aromatics with phenylmethanesulfonyl chloride in nitromethane

โœ Scribed by Covey, William D.; DeHaan, Franklin P.; Delker, Gerald L.; Dawson, Steven F.; Kilpatrick, Peter K.; Rattinger, Gail B.; Read, William G.


Book ID
127059317
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
559 KB
Volume
49
Category
Article
ISSN
0022-3263

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Vacuum line kinetic studies of the reaction of p-toluenesulfonyl chloride and benzene or toluene, using aluminum chloride as the catalyst and dichloromethane as the solvent were determined at 25ะŠC by means of gas chromatography. The reaction is first-order in arene, tosyl chloride, and in AlCl 3 as

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