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Electrophilic aromatic substitution. 6. A kinetic study of the formylation of aromatics with 1,1-dichloromethyl methyl ether in nitromethane

✍ Scribed by DeHaan, Franklin P.; Delker, Gerald L.; Covey, William D.; Bellomo, Anthony F.; Brown, Julie A.; Ferrara, Daro M.; Haubrich, Richard H.; Lander, Elliot B.; MacArthur, Carol J.

Book ID
120368747
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
510 KB
Volume
49
Category
Article
ISSN
0022-3263

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Electrophilic aromatic substitution. 14. [1] A kinetic, NMR, and Raman study of the aluminum chloride-catalyzed reaction of p-toluene-sulfonyl chloride with benzene and toluene in dichloromethane
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Vacuum line kinetic studies of the reaction of p-toluenesulfonyl chloride and benzene or toluene, using aluminum chloride as the catalyst and dichloromethane as the solvent were determined at 25ЊC by means of gas chromatography. The reaction is first-order in arene, tosyl chloride, and in AlCl 3 as