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Kinetic Study of the Self-Reactions of the BrCH 2 CH 2 O 2 and BrCH(CH 3 )CH(CH 3 )O 2 Radicals between 275 and 373 K

✍ Scribed by Villenave, Eric; Moisan, Sandy; Lesclaux, Robert


Book ID
126267381
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
121 KB
Volume
107
Category
Article
ISSN
1089-5639

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Kinetic flash spectroscopic study of the
✍ Charles S. Kan; Robert D. McQuigg; Michael R. Whitbeck; Jack G. Calvert πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 676 KB

Methylperoxy radicals were generated by the flash photolysis of azomethane-oxygen mixtures. The observed broadband spectrum of the CH302 radical is similar, but not identical to those reported previously. The CH:302 decay followed second-order kinetics a t high CH:jOz concentrations with k4, = (2.5