Kinetic Study of the Reaction of Hydrogen Atoms with Molecular Chlorine at MilliTorr Pressures
β Scribed by Dobis, Otto; Benson, Sidney W.
- Book ID
- 127253214
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 66 KB
- Volume
- 104
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The use of iodine monochloride (IC1) as a thermal source of chlorine atoms in known concentration is discussed with particular reference to the suppression, by large excesses of iodine, of the chain processes normally associated with chlorine atom reactions. The kinetics and mechanism of the reactio
Using a relative rate technique the reactions of chlorine and fluorine atoms with CF3CHO have been determined to proceed with rate constants of (1.8 % 0.4) x and (2.7 2 0.1) x lo-" cm3 molecule-' s-', respectively. Experiments were performed a t 295 ? 2 K and 700 torr total pressure of nitrogen. The