Kinetic Study of the Hexacyanoferrate (III) Oxidation of Dihydroxyfumaric Acid in Acid Media
✍ Scribed by García, B.; Ruiz, R.; Leal, J. M.
- Book ID
- 125450647
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 127 KB
- Volume
- 112
- Category
- Article
- ISSN
- 1089-5639
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## Abstract The oxidation of halotoluenes by hexacyanoferrate(III) in aqueous acetic acid containing perchloric acid (0.5__M__) at 50°C gave the corresponding aldehyde as the major product, and a small amount of polymeric material. The order with respect to each of the reactants—substrate, oxidant,
The kinetics of oxidation of sulfanilic acid (p-aminobenzenesulfonic acid) by hexacyanoferrate(III) in alkaline medium was studied spectrophotometrically. The reaction showed first order kinetics in hexacyanoferrate(III) and alkali concentrations and an order of less than unity in sulfanilic acid co