Kinetics of oxidation of phenanthrene by acidic hexacyanoferrate(III)
β Scribed by Bhattacharjee, A. K. ;Mahanti, M. K.
- Book ID
- 112683843
- Publisher
- Springer
- Year
- 1983
- Tongue
- English
- Weight
- 179 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0133-1736
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## Abstract The oxidation of halotoluenes by hexacyanoferrate(III) in aqueous acetic acid containing perchloric acid (0.5__M__) at 50Β°C gave the corresponding aldehyde as the major product, and a small amount of polymeric material. The order with respect to each of the reactantsβsubstrate, oxidant,
Kinetics of oxidation of phenylhydrazine and p-bromophenylhydrazine by hexacyanoferrate(I1If in acidic medium have been studied. The reactions follow similar kinetics, being first order with respect to both hydrazine and hexacyanoferrate(II1) and inverse first order with respect to the hydrogen ion.