The electrochemical processes of aqueous Br&-system on platimzed titanium were studied by the method of the rotating disk electrode. Both the cathodic and the anodic processes involve two consecutive electrochemical steps, comparably rate-controlling, cath I Brt + e z Br-+ Brada, f&II II oath II Bra
Kinetic study of the electrochemical processes of the bromine/bromine aqueous system on vitreous carbon electrodes
β Scribed by Marina Mastragostino; Carla Gramellini
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 546 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0013-4686
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π SIMILAR VOLUMES
The electrochemistry of solutions of lithium bromide and bromine in acetonitrile has been investigated in the temperature range from 0 to 3O"C, using a platinum rotating disk working electrode from 200 to 2000 rpm. Both the anodic and cathodic current/voltage curves are characterized by two well-de
Abstracf-The anodic and cathodic polarization curves of bromine-active carbon electrode in the fused eutectic AgBr + KBr at 400-700Β°C have been determined by the galvanostatic method. The amount of adsorbed halogen has been calculated as a function of potential and interpreted on the basis of Langmu
In this process a complex intermediate forms between the olefin and Br2 evolved and it transforms to dibromo-c-hexane. At higher potential values theelectrochemical oxidation ofthiscomplex results bromoc-hexanol, the formation of which is hindered by oxide layer on the electrode surface.