✦ LIBER ✦

Kinetic study of some elementary reactions of sulfur compounds including reactions of S and SO with OH radicals

✍ Scribed by J. L. Jourdain; G. Le Bras; J. Combourieu

Publisher: John Wiley and Sons
Year: 1979
Tongue: English
Weight: 452 KB
Volume: 11
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550110603

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✦ Synopsis

The reactions of S + OH -SO + H (1) and SO + OH -SO2 + H (2) were studied in a discharge flow reactor coupled to an EPR spectrometer. The rate constants obtained under the pseudo-first-order conditions with an excess of S or SO were found to be k l = (6.6 f 1.4) X lo-" and k p = (8.4 f 1.5) X lo-" a t room temperature. Units are cm3/molec.sec. Besides no reactivity was observed between S and COz a t 298 K and between C10 and SO2 up to 711 K.

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