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Kinetic study of reactions of some organic sulfur compounds with oh radicals

✍ Scribed by H. Mac Leod; J.L. Jourdain; G. Poulet; G. Le Bras


Book ID
113122309
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
613 KB
Volume
18
Category
Article
ISSN
0004-6981

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πŸ“œ SIMILAR VOLUMES


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The reactions of S + OH -SO + H (1) and SO + OH -SO2 + H (2) were studied in a discharge flow reactor coupled to an EPR spectrometer. The rate constants obtained under the pseudo-first-order conditions with an excess of S or SO were found to be k l = (6.6 f 1.4) X lo-" and k p = (8.4 f 1.5) X lo-" a

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Some relative rate experiments have been carried out at room temperature and at atmospheric pressure. This concerns the OH-oxidation of some oxygenated volatile organic compounds including methanol (k 1 ), ethanol (k 2 ), MTBE (k 3 ), ethyl acetate (k 4 ), n-propyl acetate (k 5 ), isopropyl acetate

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