Kinetic study of photoinitiated frontal polymerization
β Scribed by Vladimir V Ivanov; Christian Decker
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 116 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0959-8103
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The kinetics of photoinitiated polymerization of six analogous di(meth)acrylates and diacrylates was analysed according to the autocatalytic model (where is polymerization rate, p is conversion degree, R p \ kpm(1 [ p)n R p k is reaction rate constant and m and n are exponents), in order to Γnd the
## Abstract The kinetics of isothermal, photoinitiated, solution polymerization of 1βvinylβ2βmethylimidazole (MVI) was studied using the standard dilatometric technique. The photoinitiators used were aromatic carbonyl compounds. Most of the experiments were carried out using methanol as solvent, bu