The kinetics of the oxidation of mandelic acid (MA) by permanganate in aqueous alkaline medium at a constant ionic strength of 1.0 mol dm Γ3 were studied spectrophotometrically. The reaction shows first-order kinetics in [permanganate ion] and fractional order dependences in [MA] and [alkali]. Addit
Kinetic study of homogeneous acid-catalysed oxidation of certain amino-acids by potassium permanganate in moderately concentrated acidic media
β Scribed by Verma, Radhey S.; Reddy, Madhusudana J.; Shastry, Vyayendra R.
- Book ID
- 121355457
- Publisher
- Royal Society of Chemistry
- Year
- 1976
- Tongue
- English
- Weight
- 565 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1472-779X
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π SIMILAR VOLUMES
The kinetics of permanganate oxidation of L-phenylalanine in acid medium at a constant ionic strength has been investigated spectrophotometrically. An autocatalytic reaction was observed being autocatalyzed by a soluble form of Mn(1V). The reaction appears to involve a parallel consecutive reaction
The kinetic study of the oxidation of L-a-amino-n-butyric acid by permanganate ions has been carried out in buffered acid medium at pH = 1-3. using a spectrophotometric techriique An auto-catalytic effect has been observed in all cases due to Mn2+ ions formed as a product of the reaction. A first-or