Kinetic Study and Determination of the Enthalpies of Activation of the Dehydrogenation of Titanium- and Zirconium-Doped NaAlH 4 and Na 3 AlH 6
β Scribed by Kiyobayashi, Tetsu; Srinivasan, Sesha S.; Sun, Dalin; Jensen, Craig M.
- Book ID
- 121479407
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 56 KB
- Volume
- 107
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
In order to understand the final state of the TiCl 3 dopant during the dehydrogenation and rehydrogenation cycles of NaAlH 4 , we determined the reaction stoichiometry between TiCl 3 and NaAlH 4 by measuring the amount of hydrogen evolution from NaAlH 4 with the varying TiCl 3 -load. We found that:
## Abstract Areas of fusion and crystallization peaks of K3TaO2F4 and KTaF6 were measured using the DSC mode of a high-temperature calorimeter (SETARAM 1800 K). On the basis of these quantities, considering the temperature dependence of the calorimeter sensitivity, values of the fusion enthalpy of