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Determination of the enthalpy of fusion of K3TaO2F4and KTaF6

✍ Scribed by Ladislav Kosa; Iveta Macková; Zuzana Netriová


Book ID
111491259
Publisher
Versita
Year
2009
Tongue
English
Weight
272 KB
Volume
63
Category
Article
ISSN
0366-6352

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✦ Synopsis


Abstract

Areas of fusion and crystallization peaks of K3TaO2F4 and KTaF6 were measured using the DSC mode of a high-temperature calorimeter (SETARAM 1800 K). On the basis of these quantities, considering the temperature dependence of the calorimeter sensitivity, values of the fusion enthalpy of K3TaO2F4 at the fusion temperature of 1181 K of (43 ± 4) kJ mol−1 and of KTaF6 at the fusion temperature of 760 K of (8 ± 1) kJ mol−1 were determined.


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Determination of the enthalpy of fusion
✍ Ladislav Kosa; Iveta Macková 📂 Article 📅 2011 🏛 Versita 🌐 English ⚖ 252 KB

## Abstract Areas of fusion and crystallization peaks of K3NbO2F4 were measured using the DCS mode of a high-temperature calorimeter (SETARAM 1800 K). On the basis of these quantities, considering the temperature dependence of the calorimeter sensitivity, the value of the fusion enthalpy of K3NbO2F