๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Kinetic Studies on the Reactions of CF 3 with O( 3 P) and H Atoms at High Temperatures

โœ Scribed by Takahashi, Kazuo; Sekiuji, Yoshinobu; Yamamori, Yasuyuki; Inomata, Tadaaki; Yokoyama, Keiichi

Book ID
126981627
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
135 KB
Volume
102
Category
Article
ISSN
1089-5639

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Kinetics of the reaction of O(3P) with C
Kinetics of the reaction of O(3P) with CF3NO
โœ R. P. Thorn; J. M. Nicovich; J. M. Cronkhite; S. Wang; P. H. Wine ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 580 KB

A laser flash photolysis-resonance fluorescence technique has been employed to study the kinetics of the reaction of O(3P) with CF3NO (kz) as a function of temperature. Our results are described by the Arrhenius expression k z ( T ) = (4.54 ? 0.70) X 10-12exp[(-560 i 46)/T] cm3molecule-'s-' (243 K 5

Kinetic study of the reaction of chlorin
Kinetic study of the reaction of chlorine atoms with CF3I and the reactions of CF3 radicals with O2, Cl2 and NO at 296 K
โœ E. W. Kaiser; T. J. Wallington; M. D. Hurley ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 826 KB

The kinetics of the gas-phase reaction of C1 atoms with CF31 have been studied relative to the reaction of C1 atoms with CH4 over the temperature range 271-363 K. Using k(C1 + CH4) = 9.6 X exp(-2680/RT) cm3 molecule-' s-', we derive k(C1 + CF3I) = 6.25 X lo-'' exp(-2970/RT) in which E , has units of

Ab-initio study of the energetics and th
Ab-initio study of the energetics and thermodynamics of the reaction CH3H + O(3P) โ†’ CF3H โ€ฆ O โ†’ CF3 + OH
โœ W.C. Kreye ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 497 KB

Ab-initio computations at 298.15 K were made of the activation quantities AH\*, AS\*, and AG\* and of the reaction quantities AH r and AS r for is the transition state (TS). GAUSS-IAN92 was used and energies computed at a slightly modified Gaussian-2 level. Two potential surfaces for the TS had sym