Kinetic studies on the formation of ternary complexes in the reaction of diaquonitrilotriacetatonickelate(II) with amino acids in aqueous solution
β Scribed by Asim Das; Soma Gangopadhyay; Debabrata Banerjea
- Publisher
- Springer
- Year
- 1986
- Tongue
- English
- Weight
- 344 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0340-4285
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## Abstract Formation constants of ternary complexes of Cu^II^ with (__S__)βaminoβacid amides (phenylalaninamide, prolinamide, and tryptophanamide) and (__R__)β or (__S__)βamino acids (valine, phenylalanine, proline, and tryptophan) were determined potentiometrically at 25Β° and __I__ = 0.1M (KC1).
The pressure-jump method has been used to determine the rate constants for the formation and dissociation of nickel(I1) and cobalt(I1) complexes with cinchomeronate in aqueous solution at zero ionic strength. The forward and reverse rate constants obtained are k, = 2.27 x lo6 M-' s-' and k, = 3.81 x
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