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Kinetic studies on the cleavage of phthalimide in methylamine buffers

✍ Scribed by Khan, M. Niyaz ;Ohayagha, J. E.

Book ID
112686562
Publisher
Springer
Year
1996
Tongue
English
Weight
299 KB
Volume
58
Category
Article
ISSN
0133-1736

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Kinetic studies on the nucleophilic cleavage of phthalirnide [ PTH) in buffers of 2-hydroxyethylarnine and 2-rnethoxyethylarnine reveal nonlinear plots of k, vs I Bufl, (at constant pH) where k, and IBuf], represent apparent second-order rate constant and total arnine buffer concentration, respecti

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## Abstract The kinetics of the aqueous cleavage of __N__‐ethoxycarbonylphthalimide (NCPH) in CH~3~NHOH buffers of different pH reveals that the cleavage follows the general irreversible consecutive reaction path NCPH $\buildrel{k\_{1\,{\rm obs}}}\over\longrightarrow$ ENMBC $\buildrel{k\_{2\,{\rm