## Abstract The kinetics of a net twoβelectron transfer between an authentic Mn^IV^ complex, [Mn(bigH)~3~]^4+^ (__Fig.β 1__; bigHβ=βbiguanideβ=βC~2~N~5~H~7~), and nitrite in aqueous solution in the pH interval 2.00β3.60 is described. Stoichiometric data for the reaction clearly indicates Ξ[Mn^IV^]/Ξ
Kinetic studies on oxidation of l-cysteine and 2-mercaptoethanol by a trinuclear Mn(IV) species in aqueous acidic media
β Scribed by Chakraborty, Maharudra; Mandal, Pulak Chandra; Mukhopadhyay, Subrata
- Book ID
- 120079285
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 421 KB
- Volume
- 398
- Category
- Article
- ISSN
- 0020-1693
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Manganese(III) solutions were prepared by known electrochemical methods in sulfuric acid, acetic acid, and pyrophosphate media. The nature of the oxidizing species present in manganese(III) solutions was characterized by spectrophotometric and redox potential measurements. Kinetics of oxidation of L
Kinetics of oxidation of L-aspartic acid and L-glutamic acid by manganese(II1) ions have been studied in aqueous sulphuric acid, acetic acid, and pyrophosphate media. Manganese(II1) solutions were prepared by known electrolytidchemical methods in the three media. The nature of the oxidizing species
## Abstract The kinetics and mechanism of cerium(IV) oxidation of hexitols, i.e. Dβsorbitol and Dβmannitol, in aqueous sulfuric acid media have been studied in the presence and absence of surfactants. Under the kinetic conditions, [S]~T~ β« [Ce(IV)]~T~, where [S]~T~ is the total substrate (Dβsorbito