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Kinetic Studies of the thermal decomposition of ferrocenyl azide and ferrocenylsulphonyl azide in 1-chloronaphthalene

โœ Scribed by C.I. Azogu; M.N. Offor

Book ID
108351458
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
272 KB
Volume
222
Category
Article
ISSN
0022-328X

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๐Ÿ“œ SIMILAR VOLUMES

Kinetics of the thermal decomposition of
Kinetics of the thermal decomposition of ferrocenyl azide: Character of ferrocenyl nitrene
โœ C. Steel; M. Rosenblum; A. S. Geyh ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 658 KB

The Arrhenius parameters for the thermal decomposition of ferrocenyl azide in isooctane are A = (5.1 2 1.4) X 10l2 s-l and Eact = 113.1 2 0.9 (kJ mol-l) and the rate is relatively insensitive to solvent (isooctane, benzene, acetonitrile: 1:1.7:2.4). The results indicate a relatively nonpolar transit