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Kinetic studies of reactions of iron(IV)-oxo porphyrin radical cations with organic reductants

✍ Scribed by Zhengzheng Pan; Rui Zhang; Martin Newcomb


Book ID
108174929
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
252 KB
Volume
100
Category
Article
ISSN
0162-0134

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## Abstract The proximal axial ligand in heme iron enzymes plays an important role in tuning the reactivities of iron(IV)‐oxo porphyrin π‐cation radicals in oxidation reactions. The present study reports the effects of axial ligands in olefin epoxidation, aromatic hydroxylation, alcohol oxidation,