𝔖 Bobbio Scriptorium
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Kinetic studies of permanganate oxidation reactions. IV. Reaction with bromide ion

✍ Scribed by Lawani, Samuel A.; Sutter, John R.


Book ID
120068842
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
564 KB
Volume
77
Category
Article
ISSN
0022-3654

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πŸ“œ SIMILAR VOLUMES


Oxidation Reactions with β€œNaked” Permang
✍ Prof. Dr. Hans Bock; Dipl.-Chem. Dieter Jaculi πŸ“‚ Article πŸ“… 1984 πŸ› John Wiley and Sons 🌐 English βš– 323 KB

The unexpected reactivity of 1 presumably results from an electron transfer from the Pt atom to [AuPPh3]@ with subsequent elimination of H@. The resulting bimetallic PtAu intermediate could then add a further [AuPPh3]@ unit to give 3. Alternatively, a w2-H intermediate might also be involved. This w