Benzene rings severely bent and closely stacked face-to-face are revealed in the crystal structure of the [1.1]paracyclophane derivative 1, which could be isolated thanks to the kinetic stabilization provided by the steric shielding of the bridgehead sites by the substituents.
✦ LIBER ✦
Kinetic Stabilization of the [1.1]Paracyclophane System: Isolation and X-ray Structural Analysis of a [1.1]Paracyclophane Derivative and Its Interconversion with the Transannular Adduct
✍ Scribed by Hidetoshi Kawai; Takanori Suzuki; Masakazu Ohkita; Takashi Tsuji
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 215 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0947-6539
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