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Kinetic Stabilization of the [1.1]Paracyclophane System: Isolation and X-ray Structural Analysis of a [1.1]Paracyclophane Derivative and Its Interconversion with the Transannular Adduct

✍ Scribed by Hidetoshi Kawai; Takanori Suzuki; Masakazu Ohkita; Takashi Tsuji


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
215 KB
Volume
6
Category
Article
ISSN
0947-6539

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A Kinetically Stabilized [1.1]Paracyclop
✍ Hidetoshi Kawai; Takanori Suzuki; Masakazu Ohkita; Takashi Tsuji 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 112 KB 👁 1 views

Benzene rings severely bent and closely stacked face-to-face are revealed in the crystal structure of the [1.1]paracyclophane derivative 1, which could be isolated thanks to the kinetic stabilization provided by the steric shielding of the bridgehead sites by the substituents.

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