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Structure of the Cycloaddition Products of Pyrido[2,1-a]isoindole with Maleimide Derivatives: X-ray Diffraction Analysis and 1H NMR Variable-Temperature Spectra

✍ Scribed by Zoia V. Voitenko; Olexander A. Pocholenko; Oleg O. Chkarov; Oleg V. Shishkin; Svetlana V. Shishkina; Alain Dall’Ava; Marc Vedrenne; Michel Sanchez; Jean-Gérard Wolf


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
280 KB
Volume
2001
Category
Article
ISSN
1434-193X

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✦ Synopsis


Investigation of the cycloaddition reaction under thermodynamic control of pyrido[2,1-a]isoindole with maleimide derivatives revealed a new rearrangement leading to 2-{2Ј-[(1R)-2,5-dioxopyrrolidinylidene]-2Ј-[(1R)-2,5-dioxopyrrolidinyl)methyl]}phenylpyridine. Their structure was confirmed by Xray diffraction analysis. The atropisomeric properties of the