## Abstract The complexes PdCl~4~^2−^, PdCl~3~(H~2~O)^−^, and PdCl~3~(Ac)^2−^, in rapid equilibrium with each other under the adopted experimental conditions, react with ethylenediamine according to the experimental rate law A reaction scheme is proposed involving the reaction of enH^+^ with each
Kinetic spectrophotometric study of the reaction between terephthalmonohydroxamic acid and manganese(II). Determination of manganese in steels
✍ Scribed by G. Cortés; J.M. Estela; V. Cerdà; F. Salinas
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 470 KB
- Volume
- 259
- Category
- Article
- ISSN
- 0003-2670
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✦ Synopsis
AbStrsCt
The workmg conddloons affectmg the kmetlcs of formatlon of the complex between terephthalmonohydroxamlc acid and manganese were studied and ophmlzed and both classical kmetic determmatlon methods and two new methods based on semi-loganthnuc fittings of the non-linear portions of absorbance-tune curves and on theoretical equations descnbmg the kmehcs of the process were used for the detemunahon of microgram amounts of manganese The kinetic methods thus developed and the new eqmhbnum spectrophotometrlc method were applied to the determination of manganese m steels
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