𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetic spectrophotometric study of the reaction between terephthalmonohydroxamic acid and manganese(II). Determination of manganese in steels

✍ Scribed by G. Cortés; J.M. Estela; V. Cerdà; F. Salinas


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
470 KB
Volume
259
Category
Article
ISSN
0003-2670

No coin nor oath required. For personal study only.

✦ Synopsis


AbStrsCt

The workmg conddloons affectmg the kmetlcs of formatlon of the complex between terephthalmonohydroxamlc acid and manganese were studied and ophmlzed and both classical kmetic determmatlon methods and two new methods based on semi-loganthnuc fittings of the non-linear portions of absorbance-tune curves and on theoretical equations descnbmg the kmehcs of the process were used for the detemunahon of microgram amounts of manganese The kinetic methods thus developed and the new eqmhbnum spectrophotometrlc method were applied to the determination of manganese m steels


📜 SIMILAR VOLUMES


Kinetic and mechanistic study of the rea
✍ D. J. A. De Waal; W. Robb 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 456 KB

## Abstract The complexes PdCl~4~^2−^, PdCl~3~(H~2~O)^−^, and PdCl~3~(Ac)^2−^, in rapid equilibrium with each other under the adopted experimental conditions, react with ethylenediamine according to the experimental rate law A reaction scheme is proposed involving the reaction of enH^+^ with each

Kinetic and Mechanistic Studies on the O
✍ Amit Das; Subrata Mukhopadhyay 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 124 KB 👁 2 views

## Abstract The kinetics of a net two‐electron transfer between an authentic Mn^IV^ complex, [Mn(bigH)~3~]^4+^ (__Fig. 1__; bigH = biguanide = C~2~N~5~H~7~), and nitrite in aqueous solution in the pH interval 2.00–3.60 is described. Stoichiometric data for the reaction clearly indicates Δ[Mn^IV^]/Δ

Kinetic Studies on the Reaction between
✍ Dr. Riya Mukherjee; Dr. Nicola E. Brasch 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB 👁 2 views

There is currently much interest in the biochemical reactivity of peroxynitrite/peroxynitrous acid (ONOO À / ONOOH; pK a(ONOOH) = 6.8), [1] a strong oxidizing, hydroxylating and/or nitrating agent formed by the diffusion controlled reaction of nitric oxide with superoxide. [1] Elevated peroxynitrite