𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetic solvent isotope effect in aromatic nucleophilic substitution

✍ Scribed by I.R. Bellobono; P. Beltrame; M.G. Cattania; M. Simonetta

Book ID
104222860
Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
182 KB
Volume
9
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Being interested in the analogies of atio and ethylenio centera,we thought it vent isotope effect (KSIE) for hydroxylio could not find literature data on KSIE of substitution, experimental determinations nucleophilio substitutions at aromworthwhile to compare kinetic aolsolvents in. such reactions. As we any simple aromatic nuoleophilic were made.

πŸ“œ SIMILAR VOLUMES

Kinetic solvent isotope effect for aroma
Kinetic solvent isotope effect for aromatic nucleophilic substitution in mixtures of EtOH and EtOD
✍ M. G. Cattania; P. Beltrame πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 English βš– 274 KB

## Abstract Rate coefficients for the ethoxydechlorination of 1‐chloro‐2,4‐dinitrobenzene were measured in mixtures of EtOH and EtOD of different deuterium atom fraction __n__ (__n__ = 0., 0.259, 0.377, 0.581, 0.767, 0.958), at 25Β°C. The extreme solvent isotope effect, obtained by different extrapo

Solvent effects on aromatic nucleophilic
Solvent effects on aromatic nucleophilic substitution reactions. Part 9. Special kinetic synergistic behavior in binary solvent mixtures
✍ P. M. E. Mancini; A. Terenzani; C. Adam; L. R. Vottero πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 122 KB

The kinetics of the reactions of 1-fluoro-2,4-dinitrobenzene with morpholine and piperidine were studied at 25 Β°C in several binary solvent mixtures of the polar aprotic hydrogen bond acceptor solvent chloroform or dichloromethane type, which, in some cases, exhibit synergism for the E T (30) solven