Enantioselective 1,4-addition reactions of diethyl-, dimethyl-, and di-n-butylzinc to 6-methylcyclohex-2-enone (1) and 6-t-butylcyclohex-2-enone (4), catalyzed by Cu(OTf) 2 and phosphoramidites L1-L4 were examined. The additions to enone 1 proceeded with high enantioselectivity; by acid-or base-cata
β¦ LIBER β¦
Kinetic Resolution of Chiral Cyclohex-2-enones by Rhodium(I)/binap-Catalyzed 1,2- and 1,4-Additions
β Scribed by Kolb, Andreas; Hirner, Sebastian; Harms, Klaus; Zezschwitz, Paultheo von
- Book ID
- 120472244
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 493 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1523-7060
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