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Application of chiral tetrahydropentalene ligands in rhodium-catalyzed 1,4-addition of (E)-2-phenylethenyl- and (Z)-propenylboronic acids to enones

✍ Scribed by Sarah Helbig; Kirill V. Axenov; Stefan Tussetschläger; Wolfgang Frey; Sabine Laschat


Book ID
113930849
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
388 KB
Volume
53
Category
Article
ISSN
0040-4039

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Chiral Heterodisulfoxide Ligands in Rhod
✍ Fuzhong Han; Guihua Chen; Xiangyang Zhang; Jian Liao 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 379 KB 👁 1 views

## Abstract A new family of benzene‐based chiral heterodisulfoxide ligands **L1**–**L5** was synthesized in a single step. These disulfoxide ligands were applied in the rhodium‐catalyzed asymmetric 1,4‐addition of arylboronic acids to chromenones. The addition of diverse arylboronic acids to chrome